The crash occurred at about 3.30pm at the intersection of Windich Street and Brazier Street.
The female driver of the upturned Toyota Land Cruiser has been taken to hospital to have a head injury checked.
She was conscious when St John Ambulance arrived on scene.
There have been no reported injuries for the three occupants of the Subaru involved in the crash.
St John Ambulance paramedic Paul Gaughan said it was fortunate that all people involved with the accident were wearing their seatbelts.
For full details, see Wednesday's edition of the Esperance Express.